Rachael Ray: Rachael's Daytime Talkshow

Perfect Couples' Olivia Munn

Aired on: January 26, 2011

Viewers who enjoyed watching Olivia Munn as a correspondent for The Daily Show will now get to see the hilarious actress in the new NBC comedy, Perfect Couples. "I don't think I've ever been part of a perfect couple," she admits, "or else I wouldn't be the only single one on set at 3 a.m. holding lights!"

Watch the video above to see the self-proclaimed geek (and author of Suck It, Wonder Woman!) show off some of the sexy "nerdy" costumes she's worn ... from Star Trek to Return of the Jedi!